Tetrahedron Letters p. 1047 - 1050 (1980)
Update date:2022-08-04
Topics:
Kobayashi, Yoshiro
Taguchi, Takeo
Morikawa, Tsutomu
Takase, Toyohiko
Takanashi, Hiroshi
Syntheses of gem-difluorocyclopropyl ketones (3a-d) and their reactions with nucleophiles are described.Ring opening reactions of 3a, c and d with a methanolate and a thiolate anion took entirely different courses of bond scission of the cyclopropane ring.
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