A Cyclic Phosphate: Base and Metal Acetate Catalyzed Ring Opening

DOI: 10.1021/ja00344a035

Source and publish data:

Journal of the American Chemical Society p. 1631 - 1637 (1983)

Update date:2022-08-05

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Authors:

Wadsworth, William G.

Wadsworth, William S.

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Article abstract of DOI:10.1021/ja00344a035

Six-membered ring phosphates in which a good leaving group is absent undergo methanolysis to give acyclic products that can reclose to the original cyclic system.Under basic conditions the sequence is not stereospecific, which is explained by assuming an

Full text of DOI:10.1021/ja00344a035

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