Tetrahedron Letters p. 1875 - 1878 (1991)
Update date:2022-08-05
Topics:
Brueckner, Reinhard
Huisgen, Rolf
Substitution of benzylic H by the title compound (BTF) gives rise to products with -CH(CF3)2 terminus exclusively; an intermediate benzylic ion pair results from hydride transfer. Instead of ion recombination, proton transfer may be the concluding step generating dehydrogenation products and 2,2-bis(trifluoromethyl)ethane-1,1-dicarbonitrile.
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