Inorganic Chemistry p. 2169 - 2172 (1978)
Update date:2022-07-31
Topics:
Morse, Stanley D.
Shreeve, Jean'ne M.
Lithium bis(trifluoromethyl)sulfimide, LiN=S(CF3)2, is a moderately stable precursor to several new bis(trifluoromethyl)sulfimides. With (CH3)3SiCl, CF3C(O)Cl, CNCl, CF3SO2F, ClSO2F(SO2Cl2), and OPF2Cl, (CH3)3SiN=S(CF3)2, CF3C(O)N=S(CF3)2, NCN=S(CF3)2, CF3SO2N=S(CF3)2, ClSO2N=S(CF3)2, and OPF2N=S(CF3)2 are formed. The bis[bis(trifluoromethyl)sulfimides] (CH3)2Si[N=S(CF3)2]2 and CO[N=S(CF3)2]2 result with (CH3)2SiCl2 and COCl2. With the exception of the carbonyl compound which is a stable white crystalline solid, all of the sulfimides are moderately stable liquids of low volatility.
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