Chemistry Letters p. 1505 - 1508 (1982)
Update date:2022-07-30
Topics:
Miyashita, Masaaki
Yamaguchi, Ryuji
Yoshikoshi, Akira
As a convenient synthetic method of γ-keto acids, oxoalkylation of carboxylic acids with nitroolefins was examinated.Carboxylic acid dianions reacted with conjugated nitroolefins at low temperature (-100 deg C) and a variety of γ-keto acids were obtained on acidic workup in moderate to good yields.
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