Journal of Fluorine Chemistry p. 135 - 140 (1982)
Update date:2022-07-29
Topics:
Service, Colin F.
Tipping, Anthony E.
Reaction of bistrifluoromethylaminosulphenyl chloride with unsymmetrical fluoro-olefins in daylight or under photochemical conditions gives both possible 1:1 adducts (ca. 1:1) arising from homolytic fission of the S-Cl bond.Addition to octafluorobut-2-ene and hexafluorobut-2-yne gives mixtures of the syn- and anti- adducts.
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