Tetrahedron Asymmetry p. 937 - 942 (2001)
Update date:2022-08-03
Topics:
Pihko, Ainoliisa J.
Nicolaou
Koskinen, Ari M.P.
Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an α-nosyloxy ketone 7 and a highly diastereoselective C-methylation of α-azido keton
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