Stereoselective Synthesis of 1,2-cis-N-Glycosides by the N-Bromosuccinimide Promoted Reaction of Thioglycosides with Silylated Pyrimidine Bases

DOI: 10.1246/cl.1993.169

Source and publish data:

Chemistry Letters p. 169 - 172 (1993)

Update date:2022-07-30

Topics:

Authors:

Sugimura, Hideyuki

Muramoto, Ikuyo

Nakamura, Tadashi

Osumi, Kenji

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Article abstract of DOI:10.1246/cl.1993.169

The coupling of O-benzylated 1-thioglycosides, derived from D-glucose, D-mannose, D-ribose, D-xylose, and D-arabinose, with silylated pyrimidine bases by activation with N-bromosuccinimide uniformly afforded the corresponding 1,2-cis-N-glycosides with good selectivity.

Full text of DOI:10.1246/cl.1993.169

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