Tetrahedron Letters p. 1815 - 1818 (1980)
Update date:2022-07-30
Topics:
Snider, Barry B.
Rodini, David J.
Dimethylaluminum chloride which is a mild Lewis acid and a proton scavenger, catalyzes the ene reactions of aliphatic and aromatic aldehydes. Proton initiated rearrangements do not occur, since the alcohol-Lewis acid complex formed in the ene reaction rapidly to give methane and a non-acidic aluminum alkoxide.
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(2015)Doi:10.1016/S0040-4020(97)00351-7
(1997)Doi:10.1016/S0040-4039(01)84706-7
(1972)Doi:10.1039/c8gc02611d
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(2012)
