Tetrahedron Letters p. 1815 - 1818 (1980)
Update date:2022-07-30
Topics:
Snider, Barry B.
Rodini, David J.
Dimethylaluminum chloride which is a mild Lewis acid and a proton scavenger, catalyzes the ene reactions of aliphatic and aromatic aldehydes. Proton initiated rearrangements do not occur, since the alcohol-Lewis acid complex formed in the ene reaction rapidly to give methane and a non-acidic aluminum alkoxide.
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