Journal of the Chemical Society. Chemical communications p. 1453 - 1454 (1994)
Update date:2022-08-05
Topics:
Funabiki, Takuzo
Yoneda, Izumi
Ishikawa, Michiya
Ujiie, Mikio
Nagai, Yasutaka
Yoshida, Satohiro
Selective extradiol oxygenation of 3,5-di-tert-butylcatechol 1 with O2 catalysed by Fe2+ is achieved in THF in the presence of water; the different selectivity obtained by FeCl2 and FeCl3 in THF-H2O and THF-pyridine supports the explanation of the intra- and extra-diol oxygenations by Fe3+ and Fe2+, respectively, as proposed in the enzymatic systems.
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Doi:10.1021/ja01191a095
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