Nitrogen fixation. II. Dinitrogen-complexes of iron

DOI: 10.1016/S0020-1693(00)95914-0

Source and publish data:

Inorganica Chimica Acta p. 203 - 206 (1971)

Update date:2022-07-31

Topics:

Authors:

Aresta Aresta

Giannoccaro

Rossi Rossi

Sacco Sacco

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Article abstract of DOI:10.1016/S0020-1693(00)95914-0

The preparation and properties of dihydridodinitrogen complexes of iron(II), FeH₂(N₂)L₃(L=PetPh₂, PBuPh₂) are described. FeH₂(N₂)(PEtPh₂)₃ reacts with CO, to give the very stable FeH₂(CO)(PEtPh₂)₃. Both these complexes react in a 1:1 ration with AlEt₃ and possible routes of reaction are discussed.

Full text of DOI:10.1016/S0020-1693(00)95914-0

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