Journal of the Chemical Society. Perkin transactions I p. 1436 - 1449 (1980)
Update date:2022-08-03
Topics:
Jemison, Robert W.
Laird, Trevor
Ollis, W. David
Sutherland, Ian O.
The base catalysed rearrangements of diallylammonium cations and allylpropynylammonium cations are described.In most cases, the major product arises by a symmetry-allowed <3.2> sigmatropic rearrangement of the intermediate ylide.The minor products can be regarded as being derived by homolysis of the ylide into a radical pair followed by recombination.
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