Magnetic Spin Exchange Interactions between Several Metal Centres in Paramagnetic Complexes with New Polynucleating Bridging Ligands

DOI: 10.1039/c39940001273

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1273 - 1276 (1994)

Update date:2022-08-05

Topics:

Authors:

Amoroso, Angelo J.

Maher, John P.

McCleverty, Jon A.

Ward, Michael D.

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Article abstract of DOI:10.1039/c39940001273

The polynucleating bridging ligands L¹ and H3L² were simply prepared via a Heck coupling of 4-vinylpyridine or 4-methoxystyrene with 1,3,5-tribromobenzene; in the trinuclear complexes of L¹ and L² with a paramagnetic Cl> moiety at each binding site the EPR spectra demonstrate that all three unpaired electrons are in 'fast exchange' between all three metal centres.

Full text of DOI:10.1039/c39940001273

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