Tetrahedron p. 9727 - 9735 (2001)
Update date:2022-07-31
Topics:
Abad, Antonio
Agulló, Consuelo
Cu?at, Ana C
Jiménez, Diego
Perni, Remedios H
The synthesis of herbertenediol, a relevant member of the herbertane-type sesquiterpene family, is described. The synthesis is based on a new general approach to this group of sesquiterpenes where the herbertane skeleton is constructed using a Suzuki cross-coupling reaction and a [2,3]-sigmatropic Still-Wittig rearrangement as key synthetic steps.
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Doi:10.1016/S0040-4039(01)97821-9
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