Organic Letters p. 147 - 150 (2002)
Update date:2022-09-26
Topics: Optically pure Chiral Auxiliary Practical Experimental terms may include Oxocarbenium ion
Cossrow, Jennifer
Rychnovsky, Scott D.
(matrix presented) Enantiopure (S)-α-(trimethylsilyl)benzyl alcohol (98% ee) was prepared by Noyori's transfer hydrogenation of benzoyltrimethylsilane. The corresponding trimethylsilyl ether was subjected to Marko's silyl modified Sakurai conditions with
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