Reaction of Dichlorotriphenylphosphorane with Bis(trimethylsilyl) Peroxide. A new Method for the Formation of Electrophilic Chlorine Source.

DOI: 10.1246/bcsj.64.3749

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3749 - 3751 (1991)

Update date:2022-07-29

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Authors:

Shibata, Kazusato

Itoh, Yukinori

Tokitoh, Norihiro

Okazaki, Renji

Inamoto, Naoki

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Article abstract of DOI:10.1246/bcsj.64.3749

Reactions of dichlorotriphenylphosphorane with bis(trimethylsilyl) peroxide in the presence of some organic compounds have been found to give chlorinated products.Aromatic hydrocarbons bearing electron-donating substituents give the corresponding monochloroarenes, while an enol silyl ether is converted into α-chloro-ketone.The mechanism is briefly discussed.

Full text of DOI:10.1246/bcsj.64.3749

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