Bulletin of the Chemical Society of Japan p. 3749 - 3751 (1991)
Update date:2022-07-29
Topics:
Shibata, Kazusato
Itoh, Yukinori
Tokitoh, Norihiro
Okazaki, Renji
Inamoto, Naoki
Reactions of dichlorotriphenylphosphorane with bis(trimethylsilyl) peroxide in the presence of some organic compounds have been found to give chlorinated products.Aromatic hydrocarbons bearing electron-donating substituents give the corresponding monochloroarenes, while an enol silyl ether is converted into α-chloro-ketone.The mechanism is briefly discussed.
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