Preferential bond activation of sp3 C-H over sp2 C-H in α,β-unsaturated carboxylic acids by ruthenium complex

DOI: 10.1246/cl.2001.1284

Source and publish data:

Chemistry Letters p. 1284 - 1285 (2001)

Update date:2022-08-04

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Authors:

Kanaya, Susumu

Komine, Nobuyuki

Hirano, Masafumi

Komiya, Sanshiro

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Article abstract of DOI:10.1246/cl.2001.1284

Reactions of Ru(1,5-cod)(1,3,5-cot) (1)/PMe₃ [cod = cyclooctadiene, cot = cyclooctatriene] with propenoic acids (CH₂=CH(R)COOH) give unsaturated ruthenalactones Ru[OC(O)C(R)=CH-κ²O,C](PMe₃]₄ [R = Me (

Full text of DOI:10.1246/cl.2001.1284

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