Stereospecific entry to [4.5]spiroketal glycosides using alkylidenecarbene C-H insertion.

DOI: 10.1021/ol016975l

Source and publish data:

Organic letters p. 489 - 492 (2002)

Update date:2022-08-04

Topics:

Authors:

Wardrop, Duncan J

Zhang, Wenming

Fritz, Joseph

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ol016975l

[reaction: see text] A novel method for the stereospecific preparation of [4.5]spiroketal glycosides utilizing the 1,5 C-H bond insertion of alkylidenecarbenes is described. Treatment of 2-oxopropyl beta-pyranosides A with lithium (trimethylsilyl)diazomet

Full text of DOI:10.1021/ol016975l

Products guided by the article

Product name:2-oxopropyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside

Cas No:403738-05-6

R&D Labs maybe for 403738-05-6

WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Shanghai Cheerchem Co., Ltd.

Contact:86-21-50966856

Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China

Relevant to this article

1,4-Bis(arylsulfonyl)-1,2,3,4-tetrahydropyridines in synthesis. Regio- and stereoselective S_N1 reactions

Doi:10.1016/S0040-4039(01)01771-3
(2001)
Structure-activity relationships of 1′S-1′-acetoxychavicol acetate for inhibitory effect on NO production in lipopolysaccharide-activated mouse peritoneal macrophages

Doi:10.1016/j.bmcl.2005.01.070
(2005)
Solution- and solid-phase synthesis of 4-hydroxy-4,5-dihydroisoxazole serivatives from enantiomerically pure N-tosyl-2,3-aziridine alcohols

Doi:10.1021/ol0170152
(2002)
A convenient triisobutylaluminium (TIBAL)-promoted Johnson-Claisen approach to γ,δ-unsaturated alcohols

Doi:10.1055/s-0029-1217382
(2009)
SET photochemistry of phthalimide anion and its reactivity with hydrogen donors

Doi:10.1016/S0040-4020(02)00756-1
(2002)
Palladium-catalysed in situ zipper generation-cyclisation-anion capture. Synthesis of 3,3-disubstituted indolines and 2,3-dihydrobenzofurans

Doi:10.1016/S0040-4039(01)01811-1
(2001)

Article Doi