Tetrahedron p. 1225 - 1234 (1984)
Update date:2022-08-05
Topics:
Johnson, Carl R.
Zeller, James R.
The addition of the α-lithio derivative of (+)- or (-)-N,S-dimethyl-S-phenylsulfoximine to selected dl-ketones was carried out at -78 deg C in tetrahydrofuran followed by acid quench at that temperature to produce mixtures of diastereomeric β-hydroxysulfoximines.The optically-active diastereomers were chromatographically separated on silica gel.The purified diastereomers were thermolyzed at ca. 130 deg to produce optically-active ketones and the optically-active sulfoximine which could be recycled.
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Doi:10.1016/S0008-6215(00)81662-6
(1972)Doi:10.3390/molecules24081559
(2019)Doi:10.1021/jm0102755
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(2002)Doi:10.1016/j.saa.2020.118431
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