SYNTHESIS OF (Z)-1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES BY PLATINUM-CATALYSED ADDITION OF HEXAMETHYLDISTANNANE TO 1-ALKYNES

DOI: 10.1016/S0022-328X(00)98536-X

Source and publish data:

Journal of Organometallic Chemistry p. C45 - C47 (1983)

Update date:2022-07-30

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Authors:

Mitchell, T. N.

Amamria, A.

Killing, H.

Rutschow, D.

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Article abstract of DOI:10.1016/S0022-328X(00)98536-X

Addition of hexamethyldistannane to 1-alkynes in the presence of tetrakis(triphenylphosphine)palladium yields the title compounds, which can be photo-chemically isomerised to the corresponding (E)-distannylalkenes.

Full text of DOI:10.1016/S0022-328X(00)98536-X

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