Photochemical Type I and II Elimination Reactions of Dialkyl (Trichloromethyl)phosphonates

DOI: 10.1246/bcsj.53.1421

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1421 - 1424 (1980)

Update date:2022-08-05

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Authors:

Suzuki, Nobutaka

Kawai, Teruyuki

Inoue, Susumu

Sano, Naoki

Izawa, Yasuji

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Article abstract of DOI:10.1246/bcsj.53.1421

Irradiation of diisobutyl, dipropyl, and diethyl (trichloromethyl)phosphonates in MeCN gave corresponding monoesters and olefins via photochemical type II elimination.In addition, products via type I elimination were obtained from diisobutyl (trichloromethyl)phosphonate and its dimethyl ester.

Full text of DOI:10.1246/bcsj.53.1421

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