Journal of Organometallic Chemistry p. 201 - 208 (1984)
Update date:2022-08-05
Topics:
Roy, Sujit
Gupta, B. D.
Chaklanobis, Sumita
The compounds p-XC6H4SO2Cl (X = Cl, Br, I, OMe) react regiospecifically with allyl-, 2-methylallyl-, 3-methylallyl- and 3,3-dimethyl-cobaloximes under thermal and photochemical conditions.A rearranged organic product is obtained in each case.The yields are much better in photochemical reactions.A chain mechanism is involved in which the organosulphonyl radical and cobaloxime(II) are the chain propagating species.Yields of the sulphones are drastically reduced when the reactions are carried out in the presence of oxygen.
View MoreJiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Contact:86-10-62983737; +86-10-51287608
Address:4/F Building C, 2 Shangdi Xinxi Road
Shenyang Xinyihan Chemical Technology Co., Ltd.
Contact:+86-18525026267
Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Yangzhou Zhongbao Pharmaceutical Co.,Ltd
Contact:+86-514-88290838
Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Jinan YouCheng Pharmatech Co.,Ltd
Contact:+86-18653163205
Address:No.750, Shunhua Road, University Science Park, High-tech Zone, Jinan City
Doi:10.1016/j.bmcl.2007.01.110
(2007)Doi:10.1016/j.ejmech.2010.08.041
(2010)Doi:10.1016/S0014-827X(01)01148-X
(2001)Doi:10.1016/S0040-4039(01)87920-X
(1969)Doi:10.1021/ja990160e
(1999)Doi:10.1039/C39760000431
(1976)
