Journal of the Chemical Society. Perkin transactions I p. 679 - 683 (1981)
Update date:2022-08-04
Topics:
Knight, David W.
Rustidge, David C.
A general approach to 4-methyl-2-substituted-furans is described in which 4-methyl-2-furyl-lithium is the key intermediate.Using this method, pleraplysillin-2, a sesquiterpenoid ester from the sponge Pleraplysilla spinifera, has been synthesised.An alternative, less efficient, route to this type of furan, via acyclic keto-epoxides, is also discussed.
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