Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 37 - 43 (1991)
Update date:2022-08-04
Topics:
Kartasheva, Z. S.
Kasaikina, O. T.
We have obtained data on the rates of homolysis and induced decomposition of dicyclohexyldicarbonate (PC) in different types of solvents: n-decane, cyclohexane, chlorobenzene, acetonitrile.The rate of induced decomposition is determined by the activity of the radicals formed from the solvent.We have established that benzene and chlorobenzene participate in radical reactions of induced decomposition of PC, which leads to formation of a number of isomeric aryl-containing compounds.
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