STEREOSPECIFIC ALLYLSILANE REACTIONS: A TOTAL SYNTHESIS OF DIHYDRONEPETALACTONE

DOI: 10.1016/S0040-4039(01)91130-X

Source and publish data:

Tetrahedron Letters p. 5103 - 5104 (1984)

Update date:2022-08-03

Topics:

Authors:

Fleming, Ian

Terrett, Nicholas K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)91130-X

A stereospecific synthesis of allylsilanes and their stereospecific reaction with peracid are used to prepare the endo-prop-1-enylnorbornenol (6), a substrate for an oxy-Cope rearrangement leading eventually to dihydronepetalactone (10) with complete stereocontroll.

Full text of DOI:10.1016/S0040-4039(01)91130-X

Products guided by the article

Product name:Cyclopenta[c]pyran-1(3H)-one,hexahydro-4,7- dimethyl-,(4R,4aS,7R,7aS)-rel-

Cas No:4581-72-0

R&D Labs maybe for 4581-72-0

Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Nanyang Tianhua pharmaceutical Co.,Ltd.

Contact:+8618639816203

Address:Longsheng Industrial Park

Relevant to this article

Synthesis of 4-alkyl-1-benzhydryl-2-(methoxymethyl)azetidin-3-ols by regio- and stereoselective alkylation of 1-benzhydryl-3-(N-alkyl)imino-2-(methoxymethyl)azetidine

Doi:10.1016/S0040-4020(02)00178-3
(2002)
A one-pot, copper-catalyzed azidation/click reaction of aryl and heteroaryl bromides in an environmentally friendly deep eutectic solvent

Doi:10.1016/j.tet.2017.10.050
(2017)
Synthesis and characterization of Cu^II complexes with amino acid substituted di(2-pyridyl)amine ligands

Doi:10.1002/ejic.200700273
(2007)
Antiradiation compounds. I. Acylated derivatives of beta-mercaptoethylamine.

Doi:10.1002/jps.2600510219
(1962)
Doi:10.1021/ja01518a013
(1959)
The reaction of [{Co(η⁵-C₅ H₅)}₂{Fe(CO)₂(PPh₃)} (μ₃-S)(μ₃-CS)] and related complexes with carbon disulfide (see abstract)

Doi:10.1039/b308320a
(2003)

Article Doi