STEREOSPECIFIC ALLYLSILANE REACTIONS: A TOTAL SYNTHESIS OF DIHYDRONEPETALACTONE

DOI: 10.1016/S0040-4039(01)91130-X

Source and publish data:

Tetrahedron Letters p. 5103 - 5104 (1984)

Update date:2022-08-03

Topics:

Authors:

Fleming, Ian

Terrett, Nicholas K.

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Article abstract of DOI:10.1016/S0040-4039(01)91130-X

A stereospecific synthesis of allylsilanes and their stereospecific reaction with peracid are used to prepare the endo-prop-1-enylnorbornenol (6), a substrate for an oxy-Cope rearrangement leading eventually to dihydronepetalactone (10) with complete stereocontroll.

Full text of DOI:10.1016/S0040-4039(01)91130-X

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