Tetrahedron Letters p. 4003 - 4007 (2002)
Update date:2022-08-02
Topics:
Tichkowsky, Isabelle
Lett, Robert
The palladium-catalyzed coupling of the vinyldisiamylborane, formed in situ, affords the isocoumarins which can be used further for the synthesis of radicicol and related macrolides, in 72% global overall yield from the alkyne. Advantages over related vinylboronates or vinyltin couplings are discussed in the case of the present examples.
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