Tetrahedron Letters p. 6647 - 6650 (1997)
Update date:2022-07-30
Topics:
Garner, Philip
Anderson, James T.
Substitution of a t-butyl group at C-6 of the THP ring results in a chiral auxiliary that exerts exceptional stereocontrol in radical addition reactions. For example, radical 2c adds to 2-nitropropene at -78°C to give, after reductive hydrolysis, the prot
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