4592 J ournal of Medicinal Chemistry, 2002, Vol. 45, No. 21
Letters
Refer en ces
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F igu r e 4. Superposition of 1 (green) with MT-II (purple).
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F igu r e 5. Penile erections in ex copula model after iv dosing.
Vehicle (n ) 18) and 0.3 mg/kg (n ) 6) did not significantly
increase the number of erections; 1 (n ) 16), 5 (n ) 18), and
10 (n ) 6) mg/kg produced comparable increases. (///) p <
0.001, compared to vehicle treatment (paired t test).
Erectogenic activity was evaluated using an estab-
lished rodent model24-26 such that each rat served as
its own control. The mean number of erections elicited
over a 15 min period (direct visual count) in vehicle-
treated rats was 27.07 ( 1.2, n ) 64. Apomorphine, a
known erectile stimulant,24 was used as a positive
control. At 0.01 mg/kg, sc, apomorphine increased penile
erections by 37% (p < 0.001; n ) 20). Higher doses
(0.05-0.1 mg/kg, sc) did not further increase erectile
responses. Following iv administration, 1 dose-depen-
dently (0.3-10 mg/kg) increased erections (ED50 ) 0.87
mg/kg; Figure 5). The maximal increase in the number
of erections (60%) was detected at 5 mg/kg but was not
significantly different from that produced by 1 mg/kg.
Following oral administration, 1 (20 mg/kg, po) also
produced statistically significant increases in erectile
responses with a mean increase of 31 ( 4% (p < 0.001;
n ) 6).25
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Cyclic Lactam R-Melanotropin Analogues of Ac-4-Cyclo[Asp5,D-
Phe7,Lys10] R-Melanocyte-Stimulating-(4-10)-NH2 with Bulky
Aromatic Amino Acids at Position 7 Show High Antagonist
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Con clu sion . Compound 1 is the first selective small-
molecule agonist of the MC4 receptor with submicro-
molar potency to be disclosed in the literature. In vivo
testing of 1 suggests that MC4R agonism plays a role
in eliciting erectile activity in rodents. While we cannot
exclude the possibility of MC3R participation, 1 main-
tains low potency at the rodent MC3 receptor. Addition-
ally, augmentation of erectile activity observed in wild-
type mice is absent in MC4R null mice.26
(21) Bednarek, M. A.; Silve, M. V.; Arison, B.; MacNeil, T.; Kalyani,
R. N.; Huang, R. C.; Weinberg, D. H. Structure-Function
Studies on the Cyclic Peptide MT-II, Derivative of R-Melanotro-
pin. Peptides 1999, 20, 401-409.
(22) Miller, M. D.; Sheridan, R. P.; Kearsley, S. K. SQsa program
for rapidly producing pharmacophorically relevant molecular
superpositions. J . Med. Chem. 1999, 42, 1505-1514.
(23) Strack, A. M.; et al. Unpublished results.
Ack n ow led gm en t. The authors are grateful to
Falguni Patel and Mark Levorse for assistance.