Organic Letters p. 5772 - 5775 (2017)
Update date:2022-08-02
Topics:
Galloway, Jordan D.
Mai, Duy N.
Baxter, Ryan D.
A new method for silver-catalyzed Minisci reactions using Selectfluor as a mild oxidant is reported. Heteroarenes and quinones both participate in radical C-H alkylation and arylation from a variety of carboxylic and boronic acid radical precursors. Several oxidatively sensitive and highly reactive radical species are successful, providing structures that are challenging to access by other means.
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