Preparation, Spectra and X-Ray Structure of an Archetypal Coordination Compound and its Thermolysis

DOI: 10.1039/c39950000855

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 855 - 856 (1995)

Update date:2022-08-03

Topics:

Authors:

Avent, Anthony G.

Hitchcock, Peter B.

Lappert, Michael F.

Liu, Dian-Sheng

Mignani, Gerard

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950000855

Crystalline 1 is obtained in low yield from Cl and BCl3 in toluene, with trichloroborazine (BClNH)3 2 as the principal product; detailed NMR spectroscopic data on 1 in CDCl3 are consistent with the X-ray structure, which shows intermolecular hydrogen bonding with four molecules in the unit cell <(H...Cl)_av 2.76(3) Angstroem>, B-N 1.579(4), (B-Cl)_av 1.837(4) and (N-H)_av 0.86(5) Angstroem, with the boron and nitrogen environments approximately tetrahedral; thermolysis of 1 yields 2 and a TGA experiment shows that at 450 deg C boron nitride is the ultimate product.

Full text of DOI:10.1039/c39950000855

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trichloroborane-NH₃ adduct monomer

Cas No:49860-18-6

R&D Labs maybe for 49860-18-6

Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Compro Shijiazhuang Fine Chemical Co., Ltd

Contact:0086-311-89689838

Address:Economic and Technological Development Zone of Shijiazhuang,Hebei
Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.

Relevant to this article

Regioselectivity in 1,5-electrocyclization of N-[as-triazin-3-yl]nitrilimines. Synthesis of s-triazolo[4,3-b]-as-triazin-7(8H)-ones

Doi:10.1016/S0040-4020(02)00946-8
(2002)
Biosynthesis of antimalarial lignans from Holostylis reniformis

Doi:10.1016/j.phytochem.2009.02.008
(2009)
Weil-defined regioselective iminopyridine rhodium catalysts for anti-Markovnikov addition of aromatic primary amines to 1-qctyne

Doi:10.1002/adsc.200800786
(2009)
A Seleno-Pummerer Rearrangement of Haloselenuranes

Doi:10.1246/cl.1988.1317
(1988)
Additive-Free Palladium-Catalyzed Decarboxylative Cross-Coupling of Aryl Chlorides

Doi:10.1021/acs.orglett.9b01620
(2019)
Multiple bond-conjugated photoinduced nitric oxide releaser working with two-photon excitation

Doi:10.1016/j.bmcl.2009.10.120
(2010)

Article Doi