Preparation, Spectra and X-Ray Structure of an Archetypal Coordination Compound and its Thermolysis

DOI: 10.1039/c39950000855

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 855 - 856 (1995)

Update date:2022-08-03

Topics:

Authors:

Avent, Anthony G.

Hitchcock, Peter B.

Lappert, Michael F.

Liu, Dian-Sheng

Mignani, Gerard

et al. et al.

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Article abstract of DOI:10.1039/c39950000855

Crystalline 1 is obtained in low yield from Cl and BCl3 in toluene, with trichloroborazine (BClNH)3 2 as the principal product; detailed NMR spectroscopic data on 1 in CDCl3 are consistent with the X-ray structure, which shows intermolecular hydrogen bonding with four molecules in the unit cell <(H...Cl)_av 2.76(3) Angstroem>, B-N 1.579(4), (B-Cl)_av 1.837(4) and (N-H)_av 0.86(5) Angstroem, with the boron and nitrogen environments approximately tetrahedral; thermolysis of 1 yields 2 and a TGA experiment shows that at 450 deg C boron nitride is the ultimate product.

Full text of DOI:10.1039/c39950000855

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