Tetrahedron p. 6429 - 6434 (1988)
Update date:2022-08-03
Topics:
Perez, Jorge D.
Yranzo, Gloria I.
Ferraris, Marisa A.
Claramunt, Rosa M.
Lopez, Concepcion
Elguero, Jose
Flash vacuum pyrolysis of bis- and tris-(pyrazol-1-yl) methane was carried out.Alpha, gamma and radical eliminations were considered.The products actually formed correspond to a radical reaction.In the case of bis-(pyrazol-1-yl)methane, working at higher temperatures, pyrimidine was obtained.This compound is formed by rearrangement of a PzCH2. radical.
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Doi:10.1007/BF00779275
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