Compatibility studies of dimethyl(phenyl)silyl group as a masked hydroxyl group in compounds containing cyclopropane rings and in compounds containing the enone functionality

Article abstract of DOI:10.1080/00397919308011254

Compatibility of the phenyl(dimethyl)silyl group as a masked hydroxyl group in the presence of cyclopropane rings and the enone functionality was studied. The result showed that conditions for the silyl-to-hydroxyl group conversion is not compatible with cyclopropane rings. However, under a modified two-step transformation procedure, the silyl group is converted to a hydroxyl group in the presence of an enone group without disturbing the carbon-carbon double bond, to a certain extent.

Full text of DOI:10.1080/00397919308011254

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Synthetic Communications: An
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Compatibility Studies of
Dimethyl(phenyl)silyl Group
as a Masked Hydroxyl Group
in Compounds Containing
Cyclopropane Rings and in
Compounds Containing the
Enone Functionality
Noorsaadah Abd. Rahman a & Ian Fleming b
a Department of Chemistry , University of Malaya ,
59100, Kuala Lumpur, Malaysia
b University Chemical Laboratories , Lensfield Road,
Cambridge, CB2 1EW, England
Published online: 23 Sep 2006.
To cite this article: Noorsaadah Abd. Rahman & Ian Fleming (1993) Compatibility
Studies of Dimethyl(phenyl)silyl Group as a Masked Hydroxyl Group in Compounds
Containing Cyclopropane Rings and in Compounds Containing the Enone Functionality,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 23:11, 1583-1594, DOI: 10.1080/00397919308011254
To link to this article: http://dx.doi.org/10.1080/00397919308011254
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