Tetrahedron p. 2279 - 2282 (1974)
Update date:2022-08-05
Topics:
Shamma
Hwang, Der-yan
Photolysis of the phenolic tetrahydrobenzylisoquinoline 11 in basic solution yielded (±)-de-N-methylthalphenine (14). Quaternization with methyl iodide then afforded thalphenine iodide (rac. 1) which upon Hofmann elimination supplied thaliglucine (2). Thaliglucinone (3) is obtained by oxidation of thaliglucine (2).
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Doi:10.1016/j.ejmech.2010.08.030
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(2013)Doi:10.1002/hlca.19580410729
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