Journal of the Chemical Society. Perkin transactions I p. 693 - 700 (1992)
Update date:2022-07-29
Topics:
Hagiwara, Hisahiro
Kimura, Katsuhiko
Uda, Hisashi
Aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate, compound 2, with 2-benzyloxyhexanal 3c affords highly selectively (99:1) the syn-aldol adduct 4c in the presence of titanium tetrachloride.The stereocontrolled synthesis of (-)-pestalotin 7 has been achieved.
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