A STEREOSELECTIVE SYNTHESIS OF β,γ-DISUBSTITUTED ALLYLIC ALCOHOLS OF Z-CONFIGURATION

DOI: 10.1016/S0040-4039(01)90159-5

Source and publish data:

Tetrahedron Letters p. 577 - 580 (1981)

Update date:2022-08-05

Topics:

Authors:

Tamura, Mitsuhisa

Suzukamo, Gohu

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Article abstract of DOI:10.1016/S0040-4039(01)90159-5

Reaction of alkyllithiums 1 with isoprene epoxide 2 gives β,γ-disubstituted allylic alcohols 3 of Z-configuration.The reaction of ?-lithiotricyclene as alkyllithium gives α-santalol 5, which is one of the main constituents in East Indian sandalwood oil.

Full text of DOI:10.1016/S0040-4039(01)90159-5

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