Total synthesis of a cytotoxic acetogenin, pyranicin

DOI: 10.1021/ol034323m

Source and publish data:

Organic Letters p. 1353 - 1356 (2003)

Update date:2022-08-03

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Authors:

Takahashi, Shunya

Kubota, Akemi

Nakata, Tadashi

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Article abstract of DOI:10.1021/ol034323m

(Matrix presented) The first total synthesis of a new cytotoxic acetogenin, pyranicin (1), is described. Sml₂-induced reductive cyclization of β-alkoxy acrylate 4 proceeded stereoselectively to give 16,20-syn-19,20-trans-THP derivative 14, whic

Full text of DOI:10.1021/ol034323m

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