Tetrahedron Letters p. 2501 - 2504 (1980)
Update date:2022-08-03
Topics:
Erden, Ihsan
Meijere, Armin de
Rousseau, Gerard
Conia, Jean Marie
Upon photooxidation bicyclopropylidene (1) yields spiro <2.3>hexan-4-one (4) and 7-oxatrispiro<2.0.2.1>heptane (6).The formation of these is rationalized.Authentic 6 was prepared by epoxidation of 1, and 4 by isomerization of 6.
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