PHOTOOXYGENATION OF BICYCLOPROPYLIDENE

DOI: 10.1016/0040-4039(80)80111-0

Source and publish data:

Tetrahedron Letters p. 2501 - 2504 (1980)

Update date:2022-08-03

Topics:

Authors:

Erden, Ihsan

Meijere, Armin de

Rousseau, Gerard

Conia, Jean Marie

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Article abstract of DOI:10.1016/0040-4039(80)80111-0

Upon photooxidation bicyclopropylidene (1) yields spiro <2.3>hexan-4-one (4) and 7-oxatrispiro<2.0.2.1>heptane (6).The formation of these is rationalized.Authentic 6 was prepared by epoxidation of 1, and 4 by isomerization of 6.

Full text of DOI:10.1016/0040-4039(80)80111-0

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