Palladium-catalyzed allylation of alkynes with allyl alcohol in aqueous media: Highly regio- and stereoselective synthesis of 1,4-dienes

DOI: 10.1002/anie.200503970

Source and publish data:

Angewandte Chemie - International Edition p. 1945 - 1949 (2006)

Update date:2022-08-04

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Authors:

Huang, Jingmei

Zhou, Lei

Jiang, Huanfeng

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Article abstract of DOI:10.1002/anie.200503970

(Chemical Equation Presented) The direct approach: The unprecedented result of the title reaction (see scheme) is explained by a mechanism involving competition between π-allylpalladation through cleavage of the C-O bond and the insertion of an alkene. Th

Full text of DOI:10.1002/anie.200503970

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