Addition Reaction of gem-Dichloroallyl Lithium to Benzophenones in the Presence of Macrocyclic Ligands: Formation of Chloro Oxiranes

DOI: 10.1016/S0040-4020(01)85298-4

Source and publish data:

Tetrahedron p. 8161 - 8168 (1994)

Update date:2022-08-05

Topics:

Authors:

Canepa, Carlo

Prandi, Cristina

Venturello, Paolo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)85298-4

Benzophenones selectively attack the γ unsubstituted terminus of gem-dichloroallyl lithium, but show an increasing opposite selectivity for the α terminus in the presence of 12-crown-4 and cryptand <2.1.1>.The products coming from the α addition reaction

Full text of DOI:10.1016/S0040-4020(01)85298-4

Products guided by the article

Product name:Benzenemethanol, a-(3,3-dichloro-2-propenyl)-a-phenyl-

Cas No:53076-07-6

R&D Labs maybe for 53076-07-6

Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County

Relevant to this article

Preparation and configuration determination of (10R) and (10S) 10,11-dihydro-10,11-dihydroxyquinidines (metabolites of quinidine)

Doi:10.1139/v87-448
(1987)
Glutamyl-γ-boronate inhibitors of bacterial Glu-tRNA^Gln amidotransferase

Doi:10.1016/S0960-894X(01)00499-1
(2001)
SYNTHESIS AND REACTIONS OF 1-ALKYL-SUBSTITUTED 1,5-DIKETONES WITH SULFUROUS REAGENTS

Doi:10.1007/BF00503479
(1981)
REACTIVITY AND CRYSTAL AND MOLECULAR STRUCTURE OF 5-PHENYL-5-PHOSPHA-2,8-DITHIA-1-STANNA(II)BICYCLO<3.3.0^1.5>OCTANE

Doi:10.1016/S0022-328X(00)99679-7
(1986)
Efficient conjugation and preferential DNA binding of oligonucleotides containing 2′-O-(2-oxoethyl)arabinouridine

Doi:10.1016/j.tetlet.2004.08.006
(2004)
Proton-Transfer Reactions. 2. Effects of Internal Return on Reactivity Difference between Alkoxide-Promoted Eliminations in tert-Butyl alcohol and Ethyl Alcohol

Doi:10.1021/ja00408a024
(1981)

Article Doi