Chemistry Letters p. 584 - 586 (2014)
Update date:2022-07-29
Topics:
Iwai, Tomohiro
Harada, Tomoya
Tanaka, Ryotaro
Sawamura, Masaya
Silica-supported tripod triarylphosphines that have a Ph3Ptype core tripodally immobilized on a silica surface enabled the Pd-catalyzed borylation of chloroarenes with bis(pinacolato)diboron under mild conditions. The immobilization in tripod was crucial for the excellent performance of the Ph3P-based ligands.
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