Journal of the Chemical Society. Chemical communications p. 860 - 861 (1986)
Update date:2022-08-05
Topics:
Hagiwara, Hisahiro
Kimura, Katsuhiko
Uda, Hisashi
Titanium tetrachloride-mediated aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate (1) with 2-benzyloxyhexanal (3) gives highly selectively (99:1) the syn aldol adduct (5); the stereocontrolled synthesis of (-)-pestalotin (9) ha
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