Canadian Journal of Chemistry p. 2087 - 2092 (1982)
Update date:2022-08-04
Topics:
Begue, Jean-Pierre
Bonnet-Delpon, Daniele
Charpentier-Morize, Micheline
Sansoulet, Jean
This work describes stereochemical results obtained for the preparation of α-bromomethyl ketones or α-bromoaldehydes starting from monocyclic and steroid cyclohexanones, using the Durst method.In all the cases studied here, the bromine is introduced selectively in the equatorial position.However, for monocyclic compounds, the yields of α-bromocarbonyl compounds are limited by the competitive formation of α-ethylenic carbonyl compounds.
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