Kinetics of Decomposition of Rigid Diazo Compounds: Substituent Effects on the Rates of Thermolysis of 10-Diazoanthrones

DOI: 10.1021/jo00350a052

Source and publish data:

Journal of Organic Chemistry p. 5705 - 5709 (1985)

Update date:2022-08-04

Topics: Decomposition Thermolysis Kinetics Substituent Effects Rates

Authors:

Utz, Christopher G.

Shechter, Harold

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Article abstract of DOI:10.1021/jo00350a052

2-Substituted 10-diazoanthrones (4) undergo unimolecular decomposition in 1-butanol to their corresponding 10-anthronylidenes (5).Electron-donating substituents (OCH3, CH3, and Cl) at the 2-position in 4-accelerate thermolysis whereas decomposition is slo

Full text of DOI:10.1021/jo00350a052

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