Journal of Organic Chemistry p. 5705 - 5709 (1985)
Update date:2022-08-04
Topics: Decomposition Thermolysis Kinetics Substituent Effects Rates
Utz, Christopher G.
Shechter, Harold
2-Substituted 10-diazoanthrones (4) undergo unimolecular decomposition in 1-butanol to their corresponding 10-anthronylidenes (5).Electron-donating substituents (OCH3, CH3, and Cl) at the 2-position in 4-accelerate thermolysis whereas decomposition is slo
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