Stereochemistry of the α-Sulfinyl Phenylmethyl Carboanion. Reevaluation of the Configuration

DOI: 10.1021/jo00384a006

Source and publish data:

Journal of Organic Chemistry p. 1414 - 1417 (1987)

Update date:2022-08-04

Topics: Molecular structure NMR spectroscopy Spectroscopic techniques Stereochemistry X-ray crystallography

Authors:

Nakamura, Kaoru

Higaki, Masato

Adachi, Shin'ichi

Oka, Shinzaburo

Ohno, Atsuyoshi

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Article abstract of DOI:10.1021/jo00384a006

Methyl phenylmethyl sulfoxide and tert-butyl phenylmethyl sulfoxide were subjected to H-D exchange and methylation in tetrahydrofuran and water or methanol.The stereochemistry of electrophile attack depends on the reaction conditions and on the electrophi

Full text of DOI:10.1021/jo00384a006

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