Stereochemistry of the α-Sulfinyl Phenylmethyl Carboanion. Reevaluation of the Configuration

DOI: 10.1021/jo00384a006

Source and publish data:

Journal of Organic Chemistry p. 1414 - 1417 (1987)

Update date:2022-08-04

Topics: Molecular structure NMR spectroscopy Spectroscopic techniques Stereochemistry X-ray crystallography

Authors:

Nakamura, Kaoru

Higaki, Masato

Adachi, Shin'ichi

Oka, Shinzaburo

Ohno, Atsuyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00384a006

Methyl phenylmethyl sulfoxide and tert-butyl phenylmethyl sulfoxide were subjected to H-D exchange and methylation in tetrahydrofuran and water or methanol.The stereochemistry of electrophile attack depends on the reaction conditions and on the electrophi

Full text of DOI:10.1021/jo00384a006

Products guided by the article

Product name:C₈H₉⁽²⁾HO₂S

Cas No:54321-20-9

R&D Labs maybe for 54321-20-9

Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone

Relevant to this article

Synthesis of strained pyridine-containing cyclyne via reductive aromatization

Doi:10.1021/jo1006202
(2010)
Doi:10.1021/ja01118a032
(1953)
A Conceptually New Approach to the Synthesis of Linear Tetrapyrroles Related to Phytochrome

Doi:10.1016/0040-4039(95)00376-N
(1995)
Control of intramolecular π-π stacking interaction in cationic iridium complexes via fluorination of pendant phenyl rings

Doi:10.1021/ic2021325
(2012)
Total synthesis of (±)-gephyrotoxin by amide-selective reductive nucleophilic addition

Doi:10.1002/anie.201308905
(2014)
Use of 3-Hydroxy-4-(trifluoromethyl)azetidin-2-ones as Building Blocks for the Preparation of Trifluoromethyl-Containing Aminopropanes, 1,3-Oxazinan-2-ones, Aziridines, and 1,4-Dioxan-2-ones

Doi:10.1055/s-0036-1591537
(2018)

Article Doi