
Journal of Organic Chemistry p. 5457 - 5460 (1985)
Update date:2022-09-26
Topics:
Olsen, Robert J.
Pruett, Stephen R.
The photocyclization reactions of several ortho-halogenated stilbene derivatives were examined under both oxidative conditions (iodine/cyclohexane) and basic conditions (sodium methoxide/methanol).The major products were those anticipated from photodehydrogenation and photodehydrohalogenation, respectively.In some cases photodebromination of the product occurred.Some regiochemical control in phenanthrene synthesis can be achieved as is illustrated by a synthesis of dehydroorchinol acetate.
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