Tetrahedron Letters p. 1261 - 1264 (1980)
Update date:2022-08-04
Topics: Catalyzed Mechanism Oxygenation Selective Experimental
Nishinaga, A.
Tomita, H.
Matsuura, T.
The selective formation of p-quinols in the Co(Salpr)-catalyzed oxygenation of 4-alkyl-2,6-di-t-butylphenols in MeOH has been found to involve the rate determining reduction of peroxy-p-quinolato Co(III) complex formed in the initial fast step.An ionic me
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