Tetrahedron Letters (2019)
Update date:2022-08-03
Topics:
Savanur, Hemantkumar M.
Malunavar, Shruti S.
Prabhala, Pavankumar
Sutar, Suraj M.
Kalkhambkar, Rajesh G.
Laali, Kenneth K.
Chemoselective N-acylation of amines with carboxylic acids as acyl electrophiles and Br?nsted acidic IL [BMIM(SO3H)][OTf] as promoter is reported under both thermal and microwave irradiation to produce libraries of carboxamides in good to excellent yields after a simple workup. The protocol is compatible with structurally diverse 1° and 2° amines and works in the presence of sensitive functional groups such as thiols and phenols. The potential for recycling and reuse of the IL is also demonstrated.
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