Arylnitrene Cyclisations by Way of 6-Membered Spiro Intermediates. The Formation of Carbazoles, Acridines, and Acridones from Aryl 2-Azidobenzoates

DOI: 10.1039/c39800001112

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1112 - 1113 (1980)

Update date:2022-07-29

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Authors:

Clancy, Michael G.

Hesabi, Masoud M.

Meth-Cohn, Otto

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Article abstract of DOI:10.1039/c39800001112

Aryl 2-azidobenzoates undergo vapour-phase pyrolysis to give carbazoles in moderate yield: alternatively, 4-methylacridan and acridone are formed from 2,6-dimethylphenyl and salicyl 2-azidobenzoates respectively, all the products being derived from 6-membered spirobenz<1,3>oxazinone intermediates.

Full text of DOI:10.1039/c39800001112

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