Influence of the Localization of the Excitation Energy on the Photochemistry of α,β-Epoxy Ketones

DOI: 10.1021/jo00334a035

Source and publish data:

Journal of Organic Chemistry p. 4275 - 4279 (1981)

Update date:2022-09-26

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Authors:

Hallet, Philippe

Muzart, Jacques

Pete, Jean-Piere

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Article abstract of DOI:10.1021/jo00334a035

Depending on the localization of the energy, photolysis of α-epoxy ketones excited in their triplet state leads to β-diketones, α-diketones, or fragmentation products.Absorption spectra of ylide intermediates and phosphorescence spectra of α-epoxy ketones are reported.

Full text of DOI:10.1021/jo00334a035

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