Reactions of Relevance to the Chemistry of Aminoglycoside Antibiotics. Part 13. A Novel Synthesis of Benzyl Ethers

DOI: 10.1039/P19800002184

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2184 - 2190 (1980)

Update date:2022-08-03

Topics:

Authors:

Barrett, Anthony G. M.

Read, Roger W.

Barton, Derek H. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19800002184

Benzyl ethers were prepared from alcohols by reaction with chloro(phenylmethyl)dimethylammonium chloride and sodium hydrogen telluride in sequence.The salt (1) 1)OR²Cl^-; R¹=H, R²=cholest-5-en-3β-yl> and sodium borohydride gave the borane complex of 3β-dimethylaminomethoxycholest-5-ene.Salt (1; R¹=Ph, R²=cholest-5-en-3β-yl or 5α-cholestan-3β-yl) and ammonia or hydrazine gave the steroidal benzimidates or benzhydrazonate.

Full text of DOI:10.1039/P19800002184

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cholest-5-en-3β-yloxy(phenylmethylene)dimethylammonium chloride

Cas No:57701-07-2

R&D Labs maybe for 57701-07-2

Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Tai zhou world Pharm & Chem Co., Ltd

Contact:+86-576-85301198

Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Xiamen Huasing Chemicals Co.Ltd.

Contact:0086-592-6228397

Address:NO.24, Xinglin North 2nd Road,Jimei district
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China

Relevant to this article

Doi:10.1016/S0022-328X(00)86364-0
(1975)
Doi:10.1021/jm00224a012
(1976)
Further exploration of 1-{2-[Bis-(4-fluorophenyl)methoxy]ethyl}piperazine (GBR 12909): Role of N-aromatic, N-heteroaromatic, and 3-oxygenated N-phenylpropyl substituents on affinity for the dopamine and serotonin transporter

Doi:10.1016/S0960-894X(03)00108-2
(2003)
A simple one-pot procedure for the iminium salt formation: An efficient route to β-arylethylamines

Doi:10.1016/j.tetlet.2005.01.027
(2005)
Doi:10.1021/ja01239a005
(1944)
Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (-)-cucumin H

Doi:10.1021/ol034635p
(2003)

Article Doi