Reactions of Relevance to the Chemistry of Aminoglycoside Antibiotics. Part 13. A Novel Synthesis of Benzyl Ethers

DOI: 10.1039/P19800002184

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2184 - 2190 (1980)

Update date:2022-08-03

Topics:

Authors:

Barrett, Anthony G. M.

Read, Roger W.

Barton, Derek H. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19800002184

Benzyl ethers were prepared from alcohols by reaction with chloro(phenylmethyl)dimethylammonium chloride and sodium hydrogen telluride in sequence.The salt (1) 1)OR²Cl^-; R¹=H, R²=cholest-5-en-3β-yl> and sodium borohydride gave the borane complex of 3β-dimethylaminomethoxycholest-5-ene.Salt (1; R¹=Ph, R²=cholest-5-en-3β-yl or 5α-cholestan-3β-yl) and ammonia or hydrazine gave the steroidal benzimidates or benzhydrazonate.

Full text of DOI:10.1039/P19800002184

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cholest-5-en-3β-yloxy(phenylmethylene)dimethylammonium chloride

Cas No:57701-07-2

R&D Labs maybe for 57701-07-2

Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
Global United Biotechnology Inc.

Contact:+86-21-61618568

Address:Room 309, Building 6, NO.135, Jinyu Road, Pudong
Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China

Relevant to this article

Doi:10.1016/S0022-328X(00)86364-0
(1975)
Doi:10.1021/jm00224a012
(1976)
Further exploration of 1-{2-[Bis-(4-fluorophenyl)methoxy]ethyl}piperazine (GBR 12909): Role of N-aromatic, N-heteroaromatic, and 3-oxygenated N-phenylpropyl substituents on affinity for the dopamine and serotonin transporter

Doi:10.1016/S0960-894X(03)00108-2
(2003)
A simple one-pot procedure for the iminium salt formation: An efficient route to β-arylethylamines

Doi:10.1016/j.tetlet.2005.01.027
(2005)
Doi:10.1021/ja01239a005
(1944)
Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (-)-cucumin H

Doi:10.1021/ol034635p
(2003)

Article Doi